Abstract: | The magnetostructural coupling between magnetic and structure transitions plays an important role in the multifunctional applications of magentocaloric materials. In this work, ferromagnetism and magnetostructural transformation are achieved in nonmagnetic V-doped MnNiGe alloys. With simultaneously reducing the transformation temperature and converting antiferromagnetic martensite to ferromagnetic state, the magnetostructural transformation between ferromagnetic orthorhombic phase and paramagnetic hexagonal phase is established in a temperature region as large as 130 K. The magnetic-field-induced magnetostructural transformation is accompanied by considerable magnetocaloric effect. |