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高温高压条件下三氧化二硼相变过程的研究
引用本文:刘晓旸,赵旭东,侯为民,苏文辉.高温高压条件下三氧化二硼相变过程的研究[J].高压物理学报,1995,9(3).
作者姓名:刘晓旸  赵旭东  侯为民  苏文辉
作者单位:吉林大学物理系,中国科学院国际材料物理中心
摘    要: 详细考察了三氧化二硼在高温高压条件下的相变过程。研究结果表明,在高温高压条件下,三氧化二硼经历了从立方晶系向六方晶系、正交晶系和非晶相的相变。文中还比较详细地讨论了高温、高压两种因素对结构相变的影响,以及静高压熔态淬火方法在非晶态材料制备方面所具有的独到之处。

关 键 词:高压相变  三氧化二硼  非晶  高压淬火
收稿时间:1994-04-05;

TRANSFORMATION OF BORON OXIDE B_2o_3 UNDER HIGH PRESSURE AND HIGH TEMPERATURE
Liu Xiaoyang,Zhao Xudong,Hou Weimin,Su Wenhui,.TRANSFORMATION OF BORON OXIDE B_2o_3 UNDER HIGH PRESSURE AND HIGH TEMPERATURE[J].Chinese Journal of High Pressure Physics,1995,9(3).
Authors:Liu Xiaoyang  Zhao Xudong  Hou Weimin  Su Wenhui  
Institution:1. Group of Solid State Physics, Jilin University, Changchun 130023, China;2. Internativnal Center for Materials Physics, Academia Sinica, Shenyang 110015, China
Abstract:This paper describes the transformations of boron oxide B2O3 under high pressure and high temperature. We have found that boron oxide B2O3 with cubic system is transformed into hexagonal and orthorhombic B2O3 under a pressure of 5.0 GPa and a temperature of 800 ℃. Under pressure of 4.0 GPa and temperature of 1000 ℃, cubic B2O3 is transformed into amorphous state, whose colour is white. Moreover, structural changes with increasing temperature and pressure, and method of quenching from a fusing state under high static pressure are discussed.
Keywords:high  pressure transformation  boron oxide B_2O_3  amorphous  high pressurequenching  
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