The fleeting existence of the classical vinyl cation structure |
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Authors: | Panayiotis C Varras Michael G Siskos Panagiotis S Gritzapis Ioannis P Gerothanassis |
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Institution: | 1. Department of Chemistry, Section of Organic Chemistry &2. Biochemistry, University of Ioannina, Ioannina, Greece panostch@gmail.comhttps://orcid.org/0000-0003-4280-5475;4. Biochemistry, University of Ioannina, Ioannina, Greece;5. Molecular Biology and Genetics Department, Democritus University of Thrace, Dragana, Greece |
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Abstract: | ABSTRACT Using a hyperbolic function type-potential and Schrödinger’s equation transformed into a hypergeometric differential equation along with the results presented from an ab-initio CASSCF(10,11)/cc-pVTZ calculation we show that the potential well of the classical vinyl cation minimum is incapable of supporting a zero point vibrational motion for the protons. Furthermore, as opposed to the previously found transition state linking the classical and bridged vinyl cations, we suggest that it becomes a transition state for the interconversion or tautomerization of the bridged vinyl cation. |
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Keywords: | Classical vinyl cation structure vinyl cation structure vinyl cation ab-initio CASSCF protonated acetylene |
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