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| 稀土与丙氨酸、咪唑三元配合物的FTIR和UV/VIS光谱 | |
| 引用本文： | 杨一心,杨宜康,白晋涛,王党辉,王艳,马益平.稀土与丙氨酸、咪唑三元配合物的FTIR和UV/VIS光谱[J].光子学报,2002,31(9):1120-1123. |
| 作者姓名： | 杨一心 杨宜康 白晋涛 王党辉 王艳 马益平 |
| 作者单位： | 1. 西北大学化学系,西安,710069 2. 西安交通大学系统工程研究所,西安710049 3. 西北大学光子学与光子技术研究所,西北大学光电子技术省级重点开放实验室,西安,710069 4. 西北大学物理系,西安,710069 |
| 基金项目： | 陕西省科技攻关项目 (2 0 0 1K0 8-G5 )，陕西省自然科学基金 (97H0 4)，陕西省教育厅重点科技项目 (99JK1 0 )，陕西省教育厅专项基金 (0 0JK1 2 0 )资助项目 |
| 摘 要： | 用氯化稀土(La,Pr,Eu)与α-丙氨酸、咪唑固体混配体配合物以及对应稀土盐、配体α-氨基酸和咪唑进行了FTIR光谱和固体UV/VIS、水溶液UV/VIS光谱测试,分析了配合物的光谱特性,讨论了配体和Ln(Ⅲ)离子配位方式与配合物光谱的关系. |
| 关 键 词： | 稀土三元配合物 FTIR光谱 固体UV/VIS光谱 液体UV/VIS光谱 |
| 收稿时间： | 2002/1/14 |
| 修稿时间： | 2002年1月14日 |
FTIR AND UV/VIS SPECTRA OF HALOGENATED RARE EARTH WITH ALANINE AND IMIDAZOLE TERNARY COMPOUND |
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| Yang Yixin,Yang Yikang,Bai Jintao,Wang Danghui,Wang Yan,Ma Yiping.FTIR AND UV/VIS SPECTRA OF HALOGENATED RARE EARTH WITH ALANINE AND IMIDAZOLE TERNARY COMPOUND[J].Acta Photonica Sinica,2002,31(9):1120-1123. | |
| Authors: | Yang Yixin Yang Yikang Bai Jintao Wang Danghui Wang Yan Ma Yiping |
| Institution: | 1. Department of Chemistry, Northwest University, Xi′an 710069;2. Institute of System Engineening, Xi′an Jiaotong Vuiversity 710049;3. Institute of Photon-Technology, and Provincial Key Laboratory of Photoelectronic Technology, Northwest University, Xi′an 710069;4. Department of Physics, Northwest University, Xi′an 710069 |
| Abstract: | The FTIR, solid’s UV/VIS and aqueous solution’s UV/VIS spectra of halogenated rare earth(La,Pr,Eu)with α-alanine and imidazole solid ternary compound(fistly synthesized by this experiment)and its related rare earth salt,ligand α-alanine and imidazole were measured. The spectra property of the compounds was analysised. The relation between the spectrum of compound and its structure and between ligand and the coordination mode of Ln(Ⅲ)was discussed. |
| Keywords: | Ternary compound of rare earth FTIR spectra UV/VIS spectra of the solid UV/VIS spectra of the solution |
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