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近化学计量比Ce∶Mn∶LiNbO3晶体光折变性能研究
引用本文:杨春晖,许艳波,王锐,徐玉恒.近化学计量比Ce∶Mn∶LiNbO3晶体光折变性能研究[J].光子学报,2007,36(5):909-911.
作者姓名:杨春晖  许艳波  王锐  徐玉恒
作者单位:哈尔滨工业大学,应用化学系,哈尔滨,150001
基金项目:国家自然科学基金 , 黑龙江省科技攻关项目
摘    要:在LiNbO3中掺进0.015mass%MnCO3和 0.1mass%CeO2,以Czchralski法生长Li/Nb比为1.38的近化学计量比Ce∶Mn∶LiNbO3(Ce∶Mn∶SLN)晶体和Li/Nb比为0.946的同成分Ce∶Mn∶LiNbO3(Ce∶Mn∶CLN)晶体.测试了晶体的红外光谱和紫外可见吸收光谱,讨论了Ce∶Mn∶SLN晶体OH-吸收峰和吸收边移动机理.利用二波耦合光路测试了晶体的指数增益系数,Ce∶Mn∶SLN晶体指数增益系数Γ达到27 cm2-.同时,研究了Ce∶Mn∶SLN指数增益系数提高的机理.

关 键 词:Ce:Mn:LiNbO3晶体  晶体生长  指数增益系数
文章编号:1004-4213(2007)05-0909-3
收稿时间:2005-01-25
修稿时间:2005-01-25

Research on Photorefractive Properties of Near Stiometric Ce: Mn - LiNbO3 Crystals
YANG Chun-hui,XU Yan-bo,WANG Rui,XU Yu-heng.Research on Photorefractive Properties of Near Stiometric Ce: Mn - LiNbO3 Crystals[J].Acta Photonica Sinica,2007,36(5):909-911.
Authors:YANG Chun-hui  XU Yan-bo  WANG Rui  XU Yu-heng
Institution:Harbin Institute of Technology,Department of Implied Chemistry,Harbin 150001,China
Abstract:CeO2(0.1 wt%):MnCO3(0.1 wt%):LN crystals with different Li/Nb ratios( 1.38, 0.946) were grown by Czochralski method.The crystals are near stoichiometric LiNbO3(SLN)crystals when the Li/Nb ratio is 1.38, while it is congruent LiNbO3(CLN) crystals when the Li/Nb ratio is 0.946. The IR spectra and the UV-absorption spectra were tested.The mechanism of the movement of the OH- vibration peak and the absorption edge were discussed. The exponential gain coefficient of Ce∶Mn∶LN crystals were measured with two-beam coupling, which of Ce∶Mn∶SLN crystals reach to 27 cm-2, and the mechanisms of the improvement of the exponential gain coefficient were studied.
Keywords:Ce:Mn:LiNbO3 crystals  Crystal growth  The exponential gain coefficient
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