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Spectral-kinetic evidence of interaction of photochromic diarylethenes with silver nanoparticles
Authors:O I Kobeleva  T M Valova  V A Barachevskii  M M Krayushkin  B V Lichitskii  A A Dudinov  O Yu Kuznetsova  G E Adamov and E P Grebennikov
Institution:1.Photochemistry Center,Russian Academy of Sciences,Moscow,Russia;2.Zelinskii Institute of Organic Chemistry,Russian Academy of Sciences,Moscow,Russia;3.OAO Central Scientific Research Technological Institute “Tekhnomash”,Moscow,Russia
Abstract:Spectral-kinetic investigations of the photochromism of some diarylethenes with sulfur-containing substituents in dimethylsulfoxide solutions with and without silver nanoparticles are performed. It is shown that silver nanoparticles chemically interact with diarylethene molecules, which is manifested in a change in the spectral and kinetic characteristics and photodegradation efficiency.
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