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二维自组装结构中银纳米粒子的吸收光谱特征
引用本文:周群,李晓伟,周耀国,赵宏,季媛,郑军伟.二维自组装结构中银纳米粒子的吸收光谱特征[J].光散射学报,2004,16(4):346-349.
作者姓名:周群  李晓伟  周耀国  赵宏  季媛  郑军伟
作者单位:苏州大学化学系,苏州,215006
基金项目:国家自然科学基金资助项目(20073028),江苏省教委现代光学重点实验室基金
摘    要:通过静电相互作用在聚乙烯吡啶修饰的玻璃表面组装了银纳米粒子的二维结构。吸收光谱结果表明,组装银粒子间的相互作用导致银粒子的偶极子表面等离子体共振发生较大的位移,但基本不改变四极子表面等离子体共振。银粒子表面吸附分子及周围介质直接影响其表面等离子体共振。

关 键 词:银纳米粒子  自组装  吸收光谱  表面等离子体共振  表面修饰
文章编号:1004-5929(2004)04-0346-04
收稿时间:2003/7/1
修稿时间:2003年7月1日

Characteristic Absorption Spectroscopy of Silver Nanoparticles in Two-dimensional Assembled Structures
ZHOU Qun,LI Xiao-wei,ZHOU Yao-guo,ZHAO Hong,JI Yuan,ZHENG Jun-wei.Characteristic Absorption Spectroscopy of Silver Nanoparticles in Two-dimensional Assembled Structures[J].Chinese Journal of Light Scattering,2004,16(4):346-349.
Authors:ZHOU Qun  LI Xiao-wei  ZHOU Yao-guo  ZHAO Hong  JI Yuan  ZHENG Jun-wei
Institution:ZHOU Qun,LI Xiao-wei,ZHOU Yao-guo,ZHAO Hong,JI Yuan,ZHENG Jun-wei~*
Abstract:Two-dimensional structures of silver nanoparticles were assembled on polyvinylpyridine modified glass surfaces. Absorption spectra of the assemblies demonstrate that interaction between silver nanoparticles result in large shifts of dipolar surface plasmon resonance, whereas only slight effect was observed for quadrupolar surface plasmon resonance. The adsorption of molecule on the surface of the silver nanoparticles as well as surrounding media directly affect the surface plasmon resonances of the assembled silver nanoparticles.
Keywords:Silver nanoparticle  Self-assembly  Absorption spectroscopy  Surface plasmon resonance  Surface modification
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