| 二氧化锡气敏纳米粉体的红外光谱研究 |
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| 引用本文： | 赵杰,赵经贵,高山,霍丽华.二氧化锡气敏纳米粉体的红外光谱研究[J].光散射学报,2004,16(3):234-236. |
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| 作者姓名： | 赵杰 赵经贵 高山 霍丽华 |
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| 作者单位： | 黑龙江大学化学化工学院,哈尔滨,150080 |
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| 基金项目： | 国家自然科学基金(20101003)，黑龙江省自然科学基金和省海外学人重点基金资助 |
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| 摘 要： | 采用溶胶-凝胶法制备了纳米级SnO2,利用XRD和IR光谱对其晶化过程进行了详细研究。结果表明,硝酸胶溶有利于SnO2纳米晶的生成,676和545cm-1处的红外吸收分别为二氧化锡中Eu型对称的Sn-O的伸缩振动和A2u型对称的O-Sn-O变角振动,且随着纳米粉体热处理温度的升高,峰形窄化,A2u型的变角振动峰强度降低。
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| 关 键 词： | 二氧化锡 纳米粉体 红外光谱 |
| 文章编号： | 1004-5929(2004)03-0234-03 |
| 收稿时间： | 2003/7/1 |
| 修稿时间： | 2003年7月1日 |
Study on IR Spectrum of Nanosized Stannic Oxide Powder |
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| ZHAO Jie,ZHAO Jing-gui,GAO Shan,HUO Li-hua.Study on IR Spectrum of Nanosized Stannic Oxide Powder[J].Chinese Journal of Light Scattering,2004,16(3):234-236. |
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| Authors: | ZHAO Jie ZHAO Jing-gui GAO Shan HUO Li-hua |
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| Institution: | ZHAO Jie,ZHAO Jing-gui,GAO Shan,HUO Li-hua~* |
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| Abstract: | Nanosized stannic oxide powders were prepared by sol-gel technology. The crystallization process of the nano-SnO_2 was investigated by X-ray diffraction and infrared absorption spectrum. The results show that the HNO_3 peptization is benefit for the growth of nano-crystal. The Sn-O stretching vibration of E_u symmetric mode and O-Sn-O variable-angle vibration of A_(2u) symmetric mode can be observed at 676cm~(-1) and 545 cm~(-1) in IR spectrum. With the calcined temperature increasing, the peak became narrow, and the intensity of A_(2u) variable-angle vibration mode decreased. |
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| Keywords: | SnO_2 nanopowder IR spectrum |
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