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胞嘧啶吸附在粗糙银和金电极上的表面增强拉曼光谱
引用本文:吴元菲,李剑锋,吴德印,任斌,田中群.胞嘧啶吸附在粗糙银和金电极上的表面增强拉曼光谱[J].光散射学报,2006,18(4):297-301.
作者姓名:吴元菲  李剑锋  吴德印  任斌  田中群
作者单位:厦门大学化学化工学院,固体表面物理化学国家重点实验室,厦门,361005
摘    要:利用电化学伏安方法和表面增强拉曼光谱(SERS)技术研究了在-1.0V~0V的电位区间内胞嘧啶在粗糙银电极和金电极表面上的吸附行为。结果表明,在所研究的电位区间,胞嘧啶通过N3位垂直吸附在粗糙银和金电极表面,且当电位负移时吸附作用减弱。

关 键 词:表面增强拉曼光谱  银电极  金电极  胞嘧啶
文章编号:1004-5929(2006)04-0297-05
收稿时间:2005-07-01
修稿时间:2005年7月1日

SERS Study of Cytosine Adsorbed on Roughened Silver and Gold Electrodes
WU Yuan-fei,LI Jian-feng,WU De-yin,REN Bin,TIAN Zhong-qun.SERS Study of Cytosine Adsorbed on Roughened Silver and Gold Electrodes[J].Chinese Journal of Light Scattering,2006,18(4):297-301.
Authors:WU Yuan-fei  LI Jian-feng  WU De-yin  REN Bin  TIAN Zhong-qun
Institution:Department of chemistry, State Key Laboratory of Physical Chemistry of Solid Surface, Xiamen University, Xiamen 361005, China
Abstract:This paper combined the electrochemical cyclic voltammetry and the SERS technique to study the adsorption behaviors of cytosine on roughened silver and gold electrodes from -1.0 V to 0 V. The SERS results indicate that cytosine adsorbed perpendicularly via the N3-end on roughened silver and gold electrodes. The adsorption interaction becomes weak with the negative movement of the potential.
Keywords:SERS  silver electrode  gold electrode  cytosine
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