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Investigations of magnetic and dielectric properties of cupric oxide nanoparticles
Authors:Rohini S Bhalerao-Panajkar  Mandar M Shirolkar  Raja Das  Pankaj Poddar
Institution:
  • a DST Unit on Nanoscience, Department of Physics, University of Pune, Pune-411007, India
  • b Department of Engineering and Applied Sciences, Vishwakarma Institute of Information Technology, Pune-411048, India
  • c DST Unit on Nanoscience, Department of Physics, Indian Institute of Science Education and Research, Pune-411021, India
  • d Physical and Materials Chemistry Division, National Chemical Laboratory, Pune-411008, India
  • Abstract:Cupric oxide nanoparticles of ∼8-10 nm width and 40-45 nm length self assembled as large particles ∼1-1.5 μm have been investigated, in the 10-325 K temperature range, using magnetic and dielectric measurements. In magnetic measurements a single broad peak at ∼230 K in a zero field cooled sample has been observed. Coercivity, in magnetization measurements at 10 K, suggests that the nanoparticles are core-shell type particles with an antiferromagnetic core and a ferromagnetic shell. Dielectric measurements, at various frequencies from 3.7 Hz to 949 kHz, exhibit a sharp peak at 284 K followed by weak anomalies around 213 and 230 K.
    Keywords:A  CuO nanoparticles  A  Ferromagnetic  A  Dielectric  D  Ferroelectric transition
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