Crystal-field levels in UBr3 determined by neutron spectroscopy |
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Authors: | A Murasik A Furrer W Szczepaniak |
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Institution: | Institut für Reaktortechnik, Eidgenössische Technische Hochschule Zürich, CH-5303 Würenlingen, Switzerland;Insitute of Inorganic Chemistry and Metallurgy of Rare Earths, Wroclaw Technical University, 05-370 Wroclaw, Poland |
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Abstract: | Inelastic neutron scattering experiments have been performed in UBr3 in order to determine the crystal-field levels. Four transitions between the ground state and all excited states have been observed, thus the crystal-field level scheme could be unambigously assigned. The Russell-Saunders coupling scheme has been used to derive the crystal-field parameters which cannot be accounted for by a simple point charge calculation. |
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