Mössbauer study of back co-ordination in some iron complexes of 1-(2-pyridylazo)-2-naphthol and 1-(2-pyridylazo)-2-phenanthrol |
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Authors: | KB Pandeya RP Singh GL Sawhney JS Baijal |
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Institution: | Department of Chemistry, University of Delhi, Delhi-110007, India;Department of Physics and Astrophysics, University of Delhi, Delhi-110007, India |
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Abstract: | Mössbauer studies have been made on low-spin octahedral complexes of iron(II) and iron(III) formed with two terdentate ligands, viz., 1-(2-pyridylazo)-2-naphthol and 1-(2-pyridylazo)-2-phenanthrol. The data are suggestive of π-back bonding in the two iron(II) complexes. |
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