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Mössbauer study of back co-ordination in some iron complexes of 1-(2-pyridylazo)-2-naphthol and 1-(2-pyridylazo)-2-phenanthrol
Authors:KB Pandeya  RP Singh  GL Sawhney  JS Baijal
Institution:Department of Chemistry, University of Delhi, Delhi-110007, India;Department of Physics and Astrophysics, University of Delhi, Delhi-110007, India
Abstract:Mössbauer studies have been made on low-spin octahedral complexes of iron(II) and iron(III) formed with two terdentate ligands, viz., 1-(2-pyridylazo)-2-naphthol and 1-(2-pyridylazo)-2-phenanthrol. The data are suggestive of π-back bonding in the two iron(II) complexes.
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