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Electronic structure of layered uranium compounds from photoemission spectroscopy
Authors:E Guziewicz  T Durakiewicz  JJ Joyce  AJ Arko  JL Sarrao
Institution:a Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA
b Institute of Physics, Polish Academy of Sciences, Warsaw, Poland
c Ames Laboratory, Iowa State University, Ames, IA 50011, USA
d Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Wroc?aw, Poland
Abstract:We present the photoemission results of two layered tetragonal compounds, the anti-ferromagnet UAsSe and ferromagnet USb2. We observed intriguing electronic structure for both UAsSe and USb2, in which relatively dispersive and narrow 5f bands are present. In the vicinity of the Fermi edge we found a very sharp photoemission peak with dispersion of several meV along the Γ to Z direction of the Brillouin zone. We also found a broader, hybridized f-character band with dispersion of several hundred meV along the Γ to X direction. Narrow and dispersive bands in these U-based magnetic materials are reminiscent of band magnetism as previously found in some transition metals.
Keywords:Photoemission  Uranium compounds  Electronic structure  Dispersion  Hybridization
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