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Effects of ion damage on the surface of ITO films during plasma treatment
Authors:Hyunjung Shin  Chanhyung Kim  Jang-Sik Lee  Sunghan Kim
Institution:a Center for Materials and Processes of Self-Assembly and School of Advanced Materials Engineering, Kookmin University, Seoul 136-702, Republic of Korea
b DuPont Display, 6780 Cortona Dr., Santa Barbara, CA 93117, USA
Abstract:During a surface treatment using CF4/O2 gas plasma, energetic ions affected the defect structures on the top surface of ITO thin films. C-AFM and local I-V measurements showed the formation of the depleted layer after a plasma treatment with a bias of 20 W; XPS showed the creation of new defect structures. Donor concentration in the damaged top surface of the ITO films was found to be decreased. Sn-based neutral defect complexes and reduced oxygen, which could trap the electrons, have been proposed to be formed. This can also explain the increase of the work function of ITO.
Keywords:Ion damage  ITO  Conducting atomic force microscopy
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