Properties of carbon and iron modified TiO2 photocatalyst synthesized at low temperature and photodegradation of acid orange 7 under visible light |
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| Authors: | Yongmei Wu Ling Xiao |
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| Institution: | a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, PR China
b School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, PR China |
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| Abstract: | The nanoparticles of TiO2 modified with carbon and iron were synthesized by sol-gel followed solvothermal method at low temperature. Its chemical composition and optical absorption were investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), photoluminescence emission spectroscopy (PL), UV-vis absorption spectroscopy, and electron paramagnetic resonance (EPR). It was found that carbon and iron modification causes the absorption edge of TiO2 to shift the visible light region. Fe(III) cation could be doped into the matrix of TiO2, by which could hinder the recombination rate of excited electrons/holes. Superior photocatalytic activity of TiO2 modified with carbon and iron was observed for the decomposition of acid orange 7 (AO7) under visible light irradiation. The synergistic effects of carbon and iron in modified TiO2 nanoparticles were responsible for improving visible light photocatalytic activity. |
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| Keywords: | TiO2 Modification Visible light Photocatalyst Acid orange 7 |
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