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Simplified method to prepare atomically-ordered TiO2(1 1 0)-(1 × 1) surfaces with steps and terraces
Authors:Ryota Shimizu  Katsuya IwayaTakeo Ohsawa  Tetsuya HasegawaTomihiro Hashizume  Taro Hitosugi
Institution:a WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
b Department of Chemistry, The University of Tokyo, Bunkyo, Tokyo 113-0033, Japan
c Advanced Research Laboratory, Hitachi, Ltd., Saitama 350-0395, Japan
d Department of Physics, Tokyo Institute of Technology, Meguro, Tokyo 152-8551, Japan
Abstract:An effective way to prepare atomically-ordered rutile TiO2(1 1 0) surfaces that have distinct step and terrace structures suitable for oxide thin film deposition is demonstrated. Only a two-step procedure, consisting of 20% HF etching and UHV-annealing at 1100 °C, was required to yield a clean (1 × 1) structure with step and terrace structures. Investigation of the surface using scanning tunneling microscopy, low-energy electron diffraction, and Auger electron spectroscopy reveals that carbon contamination is removed at around 800 °C, and straight steps with clear terraces appear at around 1000 °C.
Keywords:Oxide electronics  Surface science  Scanning probe microscopy  TiO2(1     0)
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