Adsorption and decomposition of NO on Pt (112) |
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Institution: | 1. Faculty of Science and Technology, Science University of Tokyo, 2641 Yamazaki, Noda-shi, Chiba 278, Japan;2. Institute of Materials Science, University of Tsukuba, Tsukuba, Japan;3. National Institute of Materials and Chemical Research 1-1 Higashi, Tsukuba Ibaraki 305-8565, Japan;1. Department of Physics, University of the Free State, P.O. Box 339, Bloemfontein, ZA 9300, South Africa;2. Department of Physics, Faculty of Education, University of Khartoum, P.O. Box 321, 11115 Omdurman, Sudan;3. Photovoltaic Laboratory, Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi 110016, India;1. School of Traditional Chinese Materia Medica, Key Laboratory of Structure-Based Drug Design and Discovery, Ministry of Education, Shenyang Pharmaceutical University, Shenyang 110016, People’s Republic of China;2. School of Pharmaceutical Engineering, Shenyang Pharmaceutical University, Shenyang 110016, People’s Republic of China;3. Chinese People''s Liberation Army 210 Hospital, Dalian 116021, People’s Republic of China;1. Key Laboratory of Automobile Materials (Ministry of Education), Department of Materials Science and Engineering, Jilin University, No. 5988 Renmin Street, Changchun 130025, PR China;2. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;3. Editorial Office, Journal of Bionic Engineering, Jilin University, No. 5988 Renmin Street, Changchun 130025, PR China;1. Université de Corse - CNRS, UMR 6134 SPE, Equipe Chimie et Biomasse, Route des Sanguinaires, 20000, Ajaccio, France;2. Neuchâtel Platform of Analytical Chemistry, University of Neuchâtel, Avenue de Bellevaux 51, 2000, Neuchâtel, Switzerland |
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Abstract: | Adsorption and decomposition of NO on Pt (1 1 2) have been studied by temperature programmed desorption (TPD), ultraviolet photoelectron spectroscopy (UPS) and X-ray photoelectron spectroscopy (XPS). NO adsorbs molecularly on Pt (1 1 2) at 95 K. About half amount of NO molecules adsorbs at the terrace sites and remaining half amount adsorbs at the step sites at a full monolayer coverage. Then about half of NO molecules adsorbed at step sites decomposes at around 483 K desorbing N2, promptly. |
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