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Determination of Scaling Parameter and Dynamical Resonances in Complex-Rotated Hamiltonian Ⅰ: Theory
作者姓名:ZHAO Fang  ;ZHAO Mei-Shan
作者单位:[1]Department of Mathematics and Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, USA; [2]The James Pranck Institute and Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, USA
基金项目:Acknowledgments This work is supported in part by a grant from the Collegiate Scholars Program. One of the authors, Fang Zhao, was supported in part by VIGRE (Vertical Integration of Research and Education) at The University of Chicago.
摘    要:In this paper we present a theoretical analysis on the determination of the scaling parameter in the complex-rotated Hamiltonian, which has served as a basis for successful applications of the rigged Hilbert space theory for resonances. Based on the complex energy eigenvalue, E(θ) = ER(θ) - iГ(θ)/2, as a function of the scaling parameter θ, we find that for potential barrier scattering, the condition dГ(θI)/dθ = 0 uniquely determines the scaling parameter 8. The condition d ER (θR)/ dθ = 0 is merely a consequence of the Virial theorem and θI =θR is not a necessary condition for a resonance state. We also provide a harmonic approximation formMism for resonances in scattering over a potential barrier.

关 键 词:测定方法  标定参数  动力学  共振  哈密顿函数

Determination of Scaling Parameter and Dynamical Resonances in Complex-Rotated Hamiltonian Ⅰ: Theory
ZHAO Fang,;ZHAO Mei-Shan.Determination of Scaling Parameter and Dynamical Resonances in Complex-Rotated Hamiltonian Ⅰ: Theory[J].Communications in Theoretical Physics,2008,49(3):599-606.
Authors:ZHAO Fang ZHAO Mei-Shan
Institution:[1]Department of Mathematics and Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, USA [2]The James Pranck Institute and Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, USA
Abstract:complex-rotated Hamiltonian, potential scattering resonances, rigged Hilbert space
Keywords:complex-rotated Hamiltonian  potential scattering resonances  rigged Hilbert space
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