| 摘 要： | In our previous theoretical studies Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Lett. 371 (2003) 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO (A1П, v = 3) with inert gases, which originates from the difference between the two A-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment.
|
