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甲醇合成二甲醚催化剂的制备与催化性能
引用本文:李响,张四方,董金龙.甲醇合成二甲醚催化剂的制备与催化性能[J].光谱实验室,2009,26(3):756-759.
作者姓名:李响  张四方  董金龙
作者单位:太原师范学院化学系,太原市黄陵路19号,030031
摘    要:采用沉淀法制备CuO-ZnO-Al2O3/ZSM-5和CuO-ZnO-Al2O3-Cr2O3/ZSM-5两种催化剂,用于甲醇脱水制备二甲醚(DME)。用微反-色谱装置对催化剂进行活性评价,用XRD对催化剂进行结构表征。在本实验条件下,以铜锌氧化物的质量分数之比为1∶1,以及铬的质量百分含量为1%,350℃煅烧的催化剂的活性最高。

关 键 词:甲醇  二甲醚(DME)  催化活性

Preparation and Catalytic Activity of Catalysts for Methanol to Dimethyl Ether Conversion
LI Xiang,ZHANG Si-Fang,DONG Jin-Long.Preparation and Catalytic Activity of Catalysts for Methanol to Dimethyl Ether Conversion[J].Chinese Journal of Spectroscopy Laboratory,2009,26(3):756-759.
Authors:LI Xiang  ZHANG Si-Fang  DONG Jin-Long
Institution:Department of Chemistry;Taiyuan Normal University;Taiyuan 030031;P.R.China
Abstract:CuO-ZnO-Al2O3/ZSM-5 and CuO-ZnO-Al2O3-Cr2O3/ZSM-5 catalysts were prepared for the dehydration of methanol to dimethyl ether (DME). The micro-counter-chromatograph onlined by the catalyst for activity evaluation, the catalysts were characterized by XRD. In this experiment, the highest activeness of the catalyst is obtained at Cuo :ZnO= 1 : 1, the precentage of Cr in the catalyst is 1%, calcined at 350℃.
Keywords:Methanol  Dimethyl Ether (DME)  Catalytic Activity
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