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Au@Pt-NPs/GC修饰电极对亚硝酸根的电催化性质
引用本文:李正,马玉婷,陈翊,吴莹. Au@Pt-NPs/GC修饰电极对亚硝酸根的电催化性质[J]. 光谱实验室, 2011, 28(5): 2383-2386
作者姓名:李正  马玉婷  陈翊  吴莹
作者单位:1. 杭州市余杭区疾病预防控制中心 杭州市余杭区世纪大道西930号311100
2. 杭州市余杭区农产品监测中心 杭州市余杭区良渚镇逸盛路162号311100
3. 苏州大学化学化工学院 江苏省苏州市工业园区星湖街188号215123
摘    要:采用电化学沉积法直接制备了Au@Pt核壳纳米粒子玻碳修饰电极(Au@Pt-NPs/GC CME),通过改变合成双金属纳米粒子时的Au、Pt材料比例,考察不同材料比例的Au@Pt双金属纳米粒子修饰电极对亚硝酸根离子(NOf)的电催化氧化行为,研究表明金和铂之间存在协同催化作用,使Au@Pt-NPs比单独铂和金纳米粒子具有...

关 键 词:电催化氧化  金核铂壳纳米粒子  修饰电极  亚硝酸根离子

Electrocatalytic Properties of Au Core-Pt Shell Nanoparticle-Glassy Carbon Modified Electrode for Nitrite
LI Zheng,MA Yu-Ting,CHEN Yi,WU Ying. Electrocatalytic Properties of Au Core-Pt Shell Nanoparticle-Glassy Carbon Modified Electrode for Nitrite[J]. Chinese Journal of Spectroscopy Laboratory, 2011, 28(5): 2383-2386
Authors:LI Zheng  MA Yu-Ting  CHEN Yi  WU Ying
Affiliation:LI Zheng MA Yu-Tinga CHEN Yi WU Yingb(Yuhang District Center for Disease Control and Prevention,Hangzhou 311100,P.R.China)a(Yuhang District Supervising&Testing Center for Agricultural Product,P.R.China)b(College of Chemistry and Chemical Engineering,Suzhou University,Suzhou,Jiangsu 215123,P.R.China)
Abstract:Au@Pt core-shell nanoparticles with different scales were obtained by direct electrodeposition and proportion alteration of Au and Pt.The electrochemical behavior and electrocatalytic capability toward nitrite ion of Au@Pt-NPs glassy carbon modified electrode(Au@Pt-NPs/GC CME) which was made of different material proportion were studied.The results showed that the electrocatalytic activity was markedly enhanced for nitrite ion oxidation on the Au@Pt-NPs/GC CME,which was attributed to the cooperation between...
Keywords:Electrocatalytic Oxidation  Au@Pt-NPs  Modified Electrode  Nitrite Ion  
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