| 新型尾式卟啉-三乙胺和吡啶季铵盐的红外光谱研究 |
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| 引用本文： | 何书美,刘彦钦,韩士田,张建军.新型尾式卟啉-三乙胺和吡啶季铵盐的红外光谱研究[J].光谱实验室,2000,17(1):61-64. |
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| 作者姓名： | 何书美 刘彦钦 韩士田 张建军 |
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| 作者单位： | 1. 河北师范大学实验中心,石家庄市,050016
2. 河北师范大学化学系,石家庄市,050016 |
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| 基金项目： | 河北省教委自然科学基金 |
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| 摘 要： | 本文对新合成的三个尾式卟啉季铵盐的红外光谱吸收带进行了归属和总结。讨论了红外吸收频率随取代基不同而发生变化的原因，以及不同链长时的诱导效应对＝Ｃ－Ｏ－Ｃ键的影响。
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| 关 键 词： | 卟啉季铵盐 红外光谱 卟啉－三乙胺 吡啶季铵盐 |
| 文章编号： | 1004－8138(2000)01-0061-04 |
| 修稿时间： | 1999-07-19 |
FT-IR Studies of New Tail Porphyrin Triethylamine and Pyridine Quaternary Ammonium Salts |
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| HE Shu-Mei,LIU Yan-Qin,HAN Shi-Tian,ZHANG Jian-Jun.FT-IR Studies of New Tail Porphyrin Triethylamine and Pyridine Quaternary Ammonium Salts[J].Chinese Journal of Spectroscopy Laboratory,2000,17(1):61-64. |
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| Authors: | HE Shu-Mei LIU Yan-Qin HAN Shi-Tian ZHANG Jian-Jun |
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| Institution: | HE Shu-Mei
(Experiment Center,Hebei Normal University,Shijiazhuang 050016,P.R.China)
ZHANG Jian-Jun
(Experiment Center,Hebei Normal University,Shijiazhuang 050016,P.R.China)
LIU Yan-Qin
(Department of Chemistry,Hebei Normal University,Shijiazhuang 050016,P.R.China)
HAN Shi-Tian
(Department of Chemistry,Hebei Normal University,Shijiazhuang 050016,P.R.China) |
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| Abstract: | IR absorption bans of three new kinds of tail porphyrin quaternary ammonium salts were determined and analyzed.Reason for the change of frequency of IR absorption along with the change of replaced groups was explained.And influence of inductive effect ofN+ on band of OC Cwith different of chain length was discussed. |
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| Keywords: | New Tail Porphyrin Quaternary Ammonium Salt IR Spectra Characteristic Absorption Peak |
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