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| （FeCp_2）_（0.65）[Ni（C_3S_7）_2]的合成及电化学性质研究 | |
| 引用本文： | 王晓晖,杨建中,霍玉洁.（FeCp_2）_（0.65）[Ni（C_3S_7）_2]的合成及电化学性质研究[J].光谱实验室,2011,28(2):658-660. |
| 作者姓名： | 王晓晖 杨建中 霍玉洁 |
| 作者单位： | 1. 内蒙古民族大学化学化工学院,内蒙古通辽市西拉木伦大街996号,028043 2. 东北电网有限公司通辽供电公司,内蒙古通辽市,028000 3. 通辽职业学院,内蒙古通辽市,028046 |
| 基金项目： | 内蒙古民族大学校级计划项目 |
| 摘 要： | 合成了一种新型的导电配位型化合物（FeCp2）0.65Ni（C3S7）2]。通过EA,ICP,1H NMR,UV对该化合物进行了表征,并通过循环伏安法和变温四探针法对其电化学性质进行了研究。结果表明分子中S原子个数增多以及二茂铁阳离子（FeCp2＋）的引入有利于导电性能的提高。 |
| 关 键 词： | 导电配位型化合物 （FeCp2）0.65[Ni（C3S7）2] 合成 电化学性质 |
Synthesis of(FeCp_2)_(0.65)[Ni(C_3S_7)_2] and Study on Its Electrochemical Property |
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| WANG Xiao-Hui,YANG Jian-Zhong,HUO Yu-Jie.Synthesis of(FeCp_2)_(0.65)[Ni(C_3S_7)_2] and Study on Its Electrochemical Property[J].Chinese Journal of Spectroscopy Laboratory,2011,28(2):658-660. | |
| Authors: | WANG Xiao-Hui YANG Jian-Zhong HUO Yu-Jie |
| Institution: | WANG Xiao-Hui YANG Jian-Zhonga HUO Yu-Jieb(College of Chemistry and Chemical Engineering,Inner Mongolia University for Nationalities,Tongliao,Inner Mongolia 028043,P.R.China)a(Tongliao Power Supply Bureau,Northeast Electric Netwrk Limitid Company,Inner Mongolia 028000,P.R.China)b(Tongliao Vocation College,Inner Mongolia 028046,P.R.China) |
| Abstract: | A new type of conductive coordination compound(FeCp2)0.65Ni(C3S7)2] was synthesized,and was characterized by EA,ICP,IR,1H NMR,UV.The electrochemical property was studied by cyclic voltammetry and four probe methods.It was concluded that the electrical conductivity of the compound can be improved by increasing sulfur atoms and adding FeCp2+. |
| Keywords: | (FeCp2)0 65[Ni(C3S7)2] |
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