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激光诱导荧光技术测量OH自由基的建立和研究
引用本文:任信荣,邵可声,唐孝炎.激光诱导荧光技术测量OH自由基的建立和研究[J].光谱实验室,2000,17(2):125-128.
作者姓名:任信荣  邵可声  唐孝炎
作者单位:北京大学环境科学中心,北京市海淀区中关村,100871
基金项目:国家自然科学基金!资助项目 (批准号 :2 95772 68)
摘    要:氢氧自由基(OH)在对流层大气化学中起着重要的作用,因此,对其浓度的测量具有重要意义。本文利用气体扩张激光诱导荧光技术(FAGE)建立了OH测定系统,对其进行了标定,得到归一化荧光信号(S)与OH自由基浓度的较好的相关关系,并对可能存在的干扰进行了分析。

关 键 词:激光诱导荧光  大气化学  氢氧自由基  浓度测定
文章编号:1004-8138(2000)02-0125-004
修稿时间:1999-11-29

Establishment of OH Radical Measurement Using Laser-Induced Fluorescence Technique
REN Xin-Rong,SHAO Ke-Sheng,TANG Xiao-Yan.Establishment of OH Radical Measurement Using Laser-Induced Fluorescence Technique[J].Chinese Journal of Spectroscopy Laboratory,2000,17(2):125-128.
Authors:REN Xin-Rong  SHAO Ke-Sheng  TANG Xiao-Yan
Abstract:Hydroxyl radical(OH) plays a key role in the tropospheric chemistry,so the measurement of its concentration is very important.In this paper,an OH detection system was established based on the LIF (Laser Induced Fluorescence)technique.A calibration system was described,and the correlation between the normalized signal( S ) and OH concentration was relatively good ( R 2=0.987).The interferences probably existing in the system were discussed.
Keywords:Hydroxyl Radical  Laser  Induced Fluorescence  Atmospheric Chemistry  
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