Solvent and surfactant effect on the self-assembly and luminescence properties of ZrO2:Eu3+ nanoparticles |
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Authors: | T López-Luke E De la Rosa V H Romero C Ángles-Chávez P Salas |
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Institution: | 1. Centro de Investigaciones en óptica, A.P. 1-948, León Gto, 37160, Mexico 2. Instituto Mexicano del Petróleo, Programa de Ingeniería Molecular, A.P.11-848, Mexico, DF, 07730, Mexico 3. Centro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, A.P. 1-1010, Querétaro, Qro, 76000, Mexico
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Abstract: | ZrO2:Eu3+ nanocrystals ranging from 17 to 43 nm were prepared by the facile precipitation method with a hydrothermal process. The crystallite size was strongly influenced by the solvent composition and enhanced with the presence of surfactant. The use of ethanol combined with surfactant stabilizes 50 wt% of the monoclinic phase, while the use of water only results in 100 wt% tetragonal phase. 80% of nanobelts were obtained preparing the sample with ethanol and surfactant as a results of the self-assembly of nanoparticles. The photoluminescence emission peak centered at 606 nm dominates the emission band for nanobelts, while for nanoparticles it is dominated by a peak centered at 612 nm. Such differences were explained in terms of the site symmetry occupying Eu3+ in the host that in turn depends on the crystalline phase. Changes in the intensity ratio I(612 nm)/I(606 nm) is proposed as a tool to analyzing changes in the monoclinic/tetragonal phase composition. The calculated asymmetry ratio R=7F2/7F1~1.2 suggest a high degree of crystallinity of the prepared samples. |
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