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Preparation of MgTi2O5 nanoparticles for sonophotocatalytic degradation of triphenylmethane dyes
Institution:1. Nanomaterials and Solar Energy Conversion Lab, Department of Chemistry, National Institute of Technology, Tiruchirappalli 620 015, India;2. The Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah 21413, P.O. Box 80203, Saudi Arabia;3. Department of Energy, University of Madras, Guindy Campus, Chennai 600025, India;4. School of Chemistry, University of Melbourne, Vic 3010, Australia
Abstract:MgTi2O5 (magnesium dititanate) nanoparticles were prepared by a simple hydrothermal assisted post-annealing method and characterized with various analytical techniques. The catalytic properties (sonocatalytic, photocatalytic and sonophotocatalytic activity) were evaluated using the degradation of triphenylmethane dyes (crystal violet, basic fuchsin, and acid fuchsin). The sonophotocatalytic activity of MgTi2O5 nanoparticles towards crystal violet was found to be ~2.9 times higher than the photocatalytic activity and ~20 times higher than that of the sonocatalytic processes. In addition, the sonophotocatalytic efficiency of MgTi2O5 nanoparticles was found to be remarkable for the degradation of basic fuchsin (cationic dye) and acid fuchsin (anionic dye). The mechanism of these catalytic activities has been discussed in detail.
Keywords:Sonocatalytic  Photocatalytic  Sonophotocatalytic activity  Synergetic effect
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