An interpretation of the mean spherical approximation |
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Authors: | E Martina F del Río |
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Institution: | Universidad Autónoma Metropolitanta, Apdo. 55-534,México 13, D.F.,Mexico |
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Abstract: | The mean spherical approximation is shown to be derivable from a perturbation expansion where the reference system follows the Percur-Yevick approximation. Then the MSA may be interpreted as a first-order expansion in which the perturbation is averaged with respect to the low-density reference distribution function. This represents a generalization of an equivalent interpretation previously made with respect to the free energy of a polar fluid. |
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