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Allowed and forbiddenn=2-2 transitions of highly ionised titanium
Authors:R Glass
Institution:1. Department of Physical and Inorganic Chemistry, University of Western Australia, Nedlands, Western Australia
Abstract:Relativistic intermediate-coupling wavefunctions are used to evaluate transition energies, line strengths and transition probabilities for all allowed and forbiddenn=2-2 transitions for beryllium-like titanium ion. We have shown that to achieve a better than 1% agreement between theory and experiment for transition energies between then=2-2 levels it is not sufficient to use the three-configuration basis composed of 2s 2, 2s2p and 2p 2.
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