Effect of hydrogen enrichment of laminar ethylene diffusion flames on thermal structure and soot yields at pressures up to 10 bar

A series of high-pressure experiments were conducted to assess the influence of hydrogen enrichment of laminar diffusion flames of nitrogen-diluted ethylene on the thermal flame structure and soot yields at pressures above atmospheric. In parallel experiments, added hydrogen is replaced by helium, either in equal mole fractions or in mass fractions, to evaluate the thermal, dilution, and direct chemical interaction effects of hydrogen in soot formation. Experiments covered pressures from atmospheric to 10 bar. In the first set of experiments, conducted at 3, 6, and 10 bar pressure, base fuel was an ethylene-nitrogen mixture with 33.3% ethylene and 66.7% nitrogen (by mole as well as by mass). This base fuel was doped with either hydrogen or helium such that hydrogen and helium mass fractions and mole fractions in the fuel stream are matched in two cases. In the second set of experiments, which were conducted at 1.2 bar pressure with ethylene as the base fuel, hydrogen or helium is added such that additive mole fraction in the fuel stream was 44%. Temperature measurements in the first set of experiments indicate that, when hydrogen is added to nitrogen-diluted ethylene, the changes in the temperature field of the co-flow diffusion flames are negligible, except at lower in the flame where hydrogen added flames display slightly higher temperatures. When helium is added instead of hydrogen, however, the temperatures were measurably lower than those of the base fuel. Results show that, once the dilution effects are accounted for, the hydrogen addition to ethylene does not suppress soot formation by direct chemical interaction at elevated pressures. These findings, which are not in agreement with the previous experimental results obtained at atmospheric pressure, are discussed in terms of the higher molecular diffusivity of hydrogen and shorter residence times of high-pressure flames.