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Ion multivalence and like-charge polyelectrolyte attraction
Authors:Butler John C  Angelini Thomas  Tang Jay X  Wong Gerard C L
Institution:Department of Materials Science & Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.
Abstract:It is known empirically that multivalent ions generate attractions between like-charged polyelectrolytes, with different valence requirements for different systems. How multivalent must an ion be before it can condense a given polyelectrolyte? Using charge-tunable M13 virus rods and a family of artificial homologous "dumbbell" divalent ions of different sizes, we have constructed a multivalent ion-polyelectrolyte phase diagram, and find an experimentally motivated general criterion for like-charged attraction based on the ion valence, ion size, and the Gouy-Chapman length.
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