Vibrational spectra and crystal lattice dynamics of hexahydrates of zinc potassium and ammonium sulfates |
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Authors: | M V Barashkov A I Komyak S N Shashkov |
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Institution: | (1) Belarusian State University, 4 F. Skorina Ave., 220050 Minsk, Belarus |
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Abstract: | The IR spectra and polarized Raman spectra of crystals of hexahydrates of zinc potassium and ammonium sulfates have been obtained
experimentally at 93 K and at room temperature. The frequencies and modes of normal vibrations of the octahedral complex Zn(H2O)6]2+ have been calculated. The assignment of the observed lines of the internal and external vibrations of the crystal cell has
been made by calculations and by factor-group analysis.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 67, No. 2, pp. 162–168, March–April, 2000. |
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Keywords: | vibrational spectrum calculation crystal Tutton salts normal vibration |
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