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不同表面结构的金纳米粒子荧光性质.
引用本文:张志娟,王春霞,王永,牛书花,吕昌贵,付德刚.不同表面结构的金纳米粒子荧光性质.[J].化学物理学报,2007,20(6):796-800.
作者姓名:张志娟  王春霞  王永  牛书花  吕昌贵  付德刚
作者单位:东南大学生物电子学国家重点实验室,南京210096,东南大学生物电子学国家重点实验室,南京210096,东南大学生物电子学国家重点实验室,南京210096,东南大学生物电子学国家重点实验室,南京210096,东南大学电子科学与工程学院,南京210096,东南大学生物电子学国家重点实验室,南京210096
摘    要:"研究了具有不同表面结构的金纳米粒子:裸金纳米粒子、三苯基膦修饰的金纳米粒子、巯基丙酸表面取代的金纳米粒子的荧光性质,及其对CdSe纳米粒子的荧光猝灭作用.发现不同的金纳米粒子荧光信号受粒子表面一价金离子与配体分子之间相互作用的影响,其荧光强度对其表面分子具有强烈的敏感性;具有不同表面结构的金纳米粒子对CdSe纳米粒子的荧光猝灭作用不同,与其吸收光谱和CdSe纳米粒子发射光谱的重叠程度相关."

关 键 词:金纳米粒子,CdSe纳米粒子,荧光,表面结构
收稿时间:2007/8/30 0:00:00
修稿时间:2007/9/17 0:00:00

Fluorescent Property of Gold Nanoparticles with Different Surface Structures
Zhi-juan Zhang,Chun-xia Wang,Yong Wang,Shu-hua Niu,Chang-gui Liu and De-gang Fu.Fluorescent Property of Gold Nanoparticles with Different Surface Structures[J].Chinese Journal of Chemical Physics,2007,20(6):796-800.
Authors:Zhi-juan Zhang  Chun-xia Wang  Yong Wang  Shu-hua Niu  Chang-gui Liu and De-gang Fu
Institution:State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China,State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China,State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China,State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China,School of Electronic Science and Engineering, Southeast University, Nanjing 210096, China,State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China
Abstract:"?Fluorescence spectra of naked gold nanoparticles, triphenylphosphine stabled gold nanoparticles, and 3-mercaptopropionic acid substituted gold nanoparticles were studied. It was found that fluorescence intensities of gold nanoparticles were highly sensitive to surface molecules. The fluorescence quenching effect of these gold nanoparticles on CdSe nanoparticles was also investigated. This quenching effect was related to the overlap degree between the absorption spectra of gold nanoparticles and the emission spectrum of CdSe nanoparticles, and was surface-dependent as well. "
Keywords:Gold nanoparticle  CdSe nanopraticle  Fluorescence  Surface structure
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