| 含氧有机物催化重整制备纯氢 |
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| 引用本文： | 薛鹤,刘俊旭,夏彤岩,李全新.含氧有机物催化重整制备纯氢[J].化学物理学报,2016,29(4):481-488. |
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| 作者姓名： | 薛鹤 刘俊旭 夏彤岩 李全新 |
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| 作者单位： | 中国科学技术大学化学物理系, 中国科学院城市污染物转化重点实验室, 安徽省生物质洁净能源重点实验室, 合肥 230026,中国科学技术大学化学物理系, 中国科学院城市污染物转化重点实验室, 安徽省生物质洁净能源重点实验室, 合肥 230026,中国科学技术大学化学物理系, 中国科学院城市污染物转化重点实验室, 安徽省生物质洁净能源重点实验室, 合肥 230026,中国科学技术大学化学物理系, 中国科学院城市污染物转化重点实验室, 安徽省生物质洁净能源重点实验室, 合肥 230026 |
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| 基金项目： | This work is supported by the National Sci-Tech Support Plan (No.2014BAD02B03), the Program for Changjiang Scholars and Innovative Research Team in University and the Fundamental Research Funds for the Central Universities (No.wk2060190040). |
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| 摘 要： | 研究了一种新的利用含氧化合物制备纯氢的催化变换过程，该过程耦合了含氧化合物的催化重整、水煤气变换反应和CO2去除步骤. 详细研究了重整催化剂的筛选、反应条件以及不同的含氧化合物催化重整行为. 利用所述集成方法获得的最高氢气浓度为99.96vol%和最大转化率为97.1mol%. 此外，通过含氧化合物的解离、催化重整和水煤气变换反应研究，探讨了含氧化合物制备纯氢的相关反应路径.
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| 关 键 词： | 含氧化合物 氢气 催化重整 水煤气变换 |
| 收稿时间： | 2016/1/16 0:00:00 |
| 修稿时间： | 2016/2/22 0:00:00 |
Catalytic Transformation of Oxygenated Organic Compounds into Pure Hydrogen |
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| He Xue,Jun-xu Liu,Tong-yan Xia and Quan-xin Li.Catalytic Transformation of Oxygenated Organic Compounds into Pure Hydrogen[J].Chinese Journal of Chemical Physics,2016,29(4):481-488. |
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| Authors: | He Xue Jun-xu Liu Tong-yan Xia and Quan-xin Li |
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| Institution: | Department of Chemical Physics, Anhui Key Laboratory of Biomass Clean Energy, Key Laboratory of Urban Pollutant Conversion, Chinese Academy of Sciences, University of Science and Technology of China, Hefei 230026, China,Department of Chemical Physics, Anhui Key Laboratory of Biomass Clean Energy, Key Laboratory of Urban Pollutant Conversion, Chinese Academy of Sciences, University of Science and Technology of China, Hefei 230026, China,Department of Chemical Physics, Anhui Key Laboratory of Biomass Clean Energy, Key Laboratory of Urban Pollutant Conversion, Chinese Academy of Sciences, University of Science and Technology of China, Hefei 230026, China and Department of Chemical Physics, Anhui Key Laboratory of Biomass Clean Energy, Key Laboratory of Urban Pollutant Conversion, Chinese Academy of Sciences, University of Science and Technology of China, Hefei 230026, China |
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| Abstract: | The continual growth in transportation fuels and more strict environmental legislations have led to immense interest in developing green biomass energy. In this work, a proposed catalytic transformation of oxygenated organic compounds (related to bio-oil) into pure hydrogen was desighed, involving the catalytic reforming of oxygenated organic compounds to hydrogen-rich mixture gas followed by the conversion of CO to CO2 via the water gas reaction and the removal of CO2. The optimization of the different reforming catalyst, the reaction conditions as well as various sources of oxygenated organic compounds were investigated in detail. The production of pure hydrogen, with the H2 content up to 99.96% and the conversion of 97.1%, was achieved by the integrated catalytic transformation. The reaction pathways were addressed based on the investigation of decomposition, catalytic reforming, and the water gas reaction. |
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| Keywords: | Oxygenated organic compounds Hydrogen Catalytic reforming Water gas reaction |
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