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LaFe1-xCuxO3的光催化性及正电子湮没研究
引用本文:傅希贤,桑丽霞,白树林,杨秋华,王俊珍,孙艺环,曾淑兰.LaFe1-xCuxO3的光催化性及正电子湮没研究[J].化学物理学报,2000,13(4):503-507.
作者姓名:傅希贤  桑丽霞  白树林  杨秋华  王俊珍  孙艺环  曾淑兰
作者单位:天津大学理学院化学系
基金项目:国家自然科学基金资助课题(No.59772019)
摘    要:研究LaFeO3及微量掺铜LaFeO3的光催化活性,利用正电子湮没谱分析掺杂的影响,发现随着掺杂百分比的增加,正电子奉命逐渐下降达到一最小值,然后又上升;而光催化活性随掺杂百分比的增加逐渐上升达到最大值,然后下降,结果表明:LaFeO3掺杂后光催化活性得以提高;正电子湮没技术是研究点阵缺陷结构的有效方法之一。

关 键 词:LaFe1/xCuxO3  光催化活性  正电子湮没  结构  缺陷
收稿时间:1999/10/12 0:00:00

A Study of Positron Annihilation and Its Photocatalytic Activity of LaFe1-xCuxO3
Fu Xixian,Sang Lixi,Bai Shulin,Yang Qiuhu,Wang Junzhen,Sun Yihuan and Zeng Shulan.A Study of Positron Annihilation and Its Photocatalytic Activity of LaFe1-xCuxO3[J].Chinese Journal of Chemical Physics,2000,13(4):503-507.
Authors:Fu Xixian  Sang Lixi  Bai Shulin  Yang Qiuhu  Wang Junzhen  Sun Yihuan and Zeng Shulan
Institution:Department of Chemistry,School of Science,Tianjin University,Tianjin 300072,Department of Chemistry,School of Science,Tianjin University,Tianjin 300072,Department of Chemistry,School of Science,Tianjin University,Tianjin 300072,Department of Chemistry,School of Science,Tianjin University,Tianjin 300072,Department of Chemistry,School of Science,Tianjin University,Tianjin 300072,Department of Chemistry,School of Science,Tianjin University,Tianjin 300072,Department of Chemistry,School of Science,Tianjin University,Tianjin 300072
Abstract:The photocatalytic activity of LaFeO3 and Cu-LaFeO3 has been studied.By means of technology of positron annihilation,it is found that the positron life deceased with increasing doping atom.After reduced to minimum,the positron life raised with concentration of doping atom.Conversely,the photocatalytic activity increased with doping atom and raised to a maximum,after that,the photocatalytic activity decreased.The obtained results show that the photocatalytic activity of doped LaFeO3 is higher than undoped.The technology of positron annihilation is one of the effective method for an investigation in lattice defect structure.
Keywords:LaFe1-xCuxO3  Photocatalytic activity  Positron annihilation
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