| CH3OH/TiO2(110)界面的光电子能谱研究 |
| |
| 引用本文： | 郝群庆,王志强,戴东旭,周传耀,杨学明.CH3OH/TiO2(110)界面的光电子能谱研究[J].化学物理学报,2017,30(6):626-630. |
| |
| 作者姓名： | 郝群庆 王志强 戴东旭 周传耀 杨学明 |
| |
| 作者单位： | 中国科学院大连化学物理研究所分子反应动力学国家重点实验室, 大连 116023,中国科学院大连化学物理研究所分子反应动力学国家重点实验室, 大连 116023;西安电子科技大学物理与光电工程学院, 西安 710071,中国科学院大连化学物理研究所分子反应动力学国家重点实验室, 大连 116023,中国科学院大连化学物理研究所分子反应动力学国家重点实验室, 大连 116023,中国科学院大连化学物理研究所分子反应动力学国家重点实验室, 大连 116023 |
| |
| 基金项目： | This work was supported by the National Natural Science Foundation of China (No.21573225 and No.21703164), the Youth Innovation Promotion Association of CAS (No.2017224) and the Natural Science Foundation of Liaoning Province (No.2015020242). |
| |
| 摘 要： |
|
| 收稿时间： | 2017/11/15 0:00:00 |
| 修稿时间： | 2017/12/20 0:00:00 |
Photoelectron Spectroscopic Study of Methanol Adsorbed Rutile TiO2(110) Surface |
| |
| Qun-qing Hao,Zhi-qiang Wang,Dong-xu Dai,Chuan-yao Zhou and Xue-ming Yang.Photoelectron Spectroscopic Study of Methanol Adsorbed Rutile TiO2(110) Surface[J].Chinese Journal of Chemical Physics,2017,30(6):626-630. |
| |
| Authors: | Qun-qing Hao Zhi-qiang Wang Dong-xu Dai Chuan-yao Zhou and Xue-ming Yang |
| |
| Institution: | State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China,State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China;School of Physics and Optoelectronic Engineering, Xidian University, Xi''an 710071 China,State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China,State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China and State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China |
| |
| Abstract: | Methanol/TiO2(110) is a model system in the surface science study of photocatalysis where methanol is taken as a hole capture. However, the highest occupied molecular orbital of adsorbed methanol lies below the valence band maximum of TiO2, preventing the hole transfer. To study the level alignment of this system, electronic structure of methanol covered TiO2(110) surface has been measured by ultraviolet photoelectron spectroscopy and the molecular orbitals of adsorbed methanol have been clearly identified. The results indicate the weak interaction between methanol and TiO2 substrate. The static electronic structure also suggests the mismatch of the energy levels. These static experiments have been performed without band gap excitation which is the prerequisite of a photocatalytic process. Future study of the transient electronic structure using time-resolved UPS has also been discussed. |
| |
| Keywords: | Methanol TiO2 Ultraviolet photoelectron spectroscopy Level alignment |
|
| 点击此处可从《化学物理学报》浏览原始摘要信息 |
| 点击此处可从《化学物理学报》下载免费的PDF全文 |
|
