| 木质素催化转化制备异丙苯 |
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| 引用本文： | 金凤,范明慧,贾启芳,李全新.木质素催化转化制备异丙苯[J].化学物理学报,2017,30(3):348-356. |
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| 作者姓名： | 金凤 范明慧 贾启芳 李全新 |
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| 作者单位： | 中国科学技术大学化学物理系, 安徽省生物质洁净能源重点实验室, 中国科学院城市污染物转化重点实验室, 合肥 230026,安徽烟草化学重点实验室, 安徽中烟工业有限责任公司, 合肥 230088,中国科学技术大学化学物理系, 安徽省生物质洁净能源重点实验室, 中国科学院城市污染物转化重点实验室, 合肥 230026,中国科学技术大学化学物理系, 安徽省生物质洁净能源重点实验室, 中国科学院城市污染物转化重点实验室, 合肥 230026 |
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| 基金项目： | This work was supported by the National Key Basic Program of China (No.2013CB228105),the Program for Changjiang Scholars and Innovative Research Team in University and the Fundamental Research Funds for the Central Universities (No.wk2060190040). |
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| 摘 要： | Cumene is an important intermediate and chemical in chemical industry.In this work,directional preparation of cumene using lignin was achieved by a three-step cascade process.The mixture aromatics were first produced by the catalytic pyrolysis of lignin at 450℃ over 1% Zn/HZSM-5 catalyst,monocyclic aromatics with the selectivity of 85.7 wt% were obtained.Then,the catalytic dealkylation of heavier aromatics resulted in benzene-rich aromatics with 93.6 wt% benzene at 600℃ over Hβ catalyst.Finally,the cumene synthesis was performed by the aromatic alkylation,giving cumene selectivity of 91.6 C-mol% using thebmim]Cl-2AlCl13 ionic liquid at room temperature for 15 min.Besides,adding a small amount of methanol to the feed can efficiently suppress the coke yield and enhance the aromatics yield.The proposed transformation potentially provides a useful route for production of cumene using renewable lignin.
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| 收稿时间： | 2017/3/17 0:00:00 |
| 修稿时间： | 2017/4/10 0:00:00 |
Synthesis of Cumene from Lignin by Catalytic Transformation |
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| Feng Jin,Ming-hui Fan,Qi-fang Jia and Quan-xin Li.Synthesis of Cumene from Lignin by Catalytic Transformation[J].Chinese Journal of Chemical Physics,2017,30(3):348-356. |
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| Authors: | Feng Jin Ming-hui Fan Qi-fang Jia and Quan-xin Li |
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| Institution: | Department of Chemical Physics, Key Laboratory of Urban Polxlutant Conversion, Chinese Academy of Sciences, Anhui Key Laboratory of Biomass Clean Energy, University of Science and Technology of China, Hefei 230026, China,Anhui Key Laboratory of Tobacco Chemistry, China Tobacco Anhui Industrial. Co., LTD, Hefei 230088, China,Department of Chemical Physics, Key Laboratory of Urban Polxlutant Conversion, Chinese Academy of Sciences, Anhui Key Laboratory of Biomass Clean Energy, University of Science and Technology of China, Hefei 230026, China and Department of Chemical Physics, Key Laboratory of Urban Polxlutant Conversion, Chinese Academy of Sciences, Anhui Key Laboratory of Biomass Clean Energy, University of Science and Technology of China, Hefei 230026, China |
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| Abstract: | |
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| Keywords: | Lignin Cumene Catalytic pyrolysis Dealkylation Alkylation |
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