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用纳米压痕法分析溶剂对聚醚醚酮(PEEK)力学性能的影响
作者姓名:TanveerIqbal  Saima Yasin  Ahmad Shakeel  Hamayoun Mahmoo  Fahad Nazir  Paul F. Luckham
作者单位:巴基斯坦拉合尔工程技术大学KSK校区, 化学聚合物与复合材料工程系 54890,巴基斯坦拉合尔工程技术大学KSK校区, 化学聚合物与复合材料工程系 54890,巴基斯坦拉合尔工程技术大学KSK校区, 化学聚合物与复合材料工程系 54890,巴基斯坦拉合尔工程技术大学KSK校区, 化学聚合物与复合材料工程系 54890,巴基斯坦拉合尔工程技术大学KSK校区, 化学聚合物与复合材料工程系 54890,伦敦帝国理工学院化学工程与技术系, 南肯辛顿, SW7 2 AZ
摘    要:

收稿时间:2017/9/18 0:00:00
修稿时间:2017/12/20 0:00:00

Analysis of Solvent Effect on Mechanical Properties of Poly(ether ether ketone) Using Nano-indentation
TanveerIqbal,Saima Yasin,Ahmad Shakeel,Hamayoun Mahmoo,Fahad Nazir,Paul F. Luckham.Analysis of Solvent Effect on Mechanical Properties of Poly(ether ether ketone) Using Nano-indentation[J].Chinese Journal of Chemical Physics,2018,31(2):211-215.
Authors:Tanveer Iqbal  Saima Yasin  Ahmad Shakeel  Hamayoun Mahmoo  Fahad Nazir and Paul F Luckham
Institution:Department of Chemical, Polymer & Composite Materials Engineering, University of Engineering & Technology, Lahore, KSK Campus, 54890, Pakistan,Department of Chemical, Polymer & Composite Materials Engineering, University of Engineering & Technology, Lahore, KSK Campus, 54890, Pakistan,Department of Chemical, Polymer & Composite Materials Engineering, University of Engineering & Technology, Lahore, KSK Campus, 54890, Pakistan,Department of Chemical, Polymer & Composite Materials Engineering, University of Engineering & Technology, Lahore, KSK Campus, 54890, Pakistan,Department of Chemical, Polymer & Composite Materials Engineering, University of Engineering & Technology, Lahore, KSK Campus, 54890, Pakistan and Department of Chemical Engineering & Technology, Imperial College London, South Kensington, SW7 2 AZ, UK
Abstract:Poly (ether ether ketone)(PEEK) is a high-performance semi-crystalline thermoplastic polymer.Exposure of the polymeric surface to solvents can have a strong effect like softening/swelling of polymeric network or dissolution.In this study,nano-indentation analysis was performed to study the effect of acetone on the surface mechanical properties of PEEK using different exposure time.The experiments were performed with a constant loading rate (10 nm/s) to a maximum indentation displacement (1000 nm).A 30-second hold segment was included at the maximum load to account for any creep effects followed by an unloading segment to 80% unloading.The indentation hardness and the elastic modulus were computed as a continuous function of the penetration displacement in the continuous stiffness mode (CSM) indentation.The experimental data showed that the peak load decreased from ~5.2 mN to ~1.7 mN as exposure time in solvent environment increased from 0 to 18 days.The elastic modulus and the hardness of PEEK samples also displayed a decreasing trend as a function of exposure time in the solvent environment.Two empirical models were used to fit the experimental data of hardness as a function of exposure time which showed a good agreement with the experimental values.
Keywords:Solvent  Nano-indentation  Poly (ether ether ketone)  Modulus  Hardness
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