| 单光子LIF方法研究亚硝基苯266 nm光解动力学 |
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| 引用本文： | 孙巨龙,李亚民,陈茂笃,韩克利,李学初,何国钟,楼南泉.单光子LIF方法研究亚硝基苯266 nm光解动力学[J].化学物理学报,2001,14(2):129-134. |
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| 作者姓名： | 孙巨龙 李亚民 陈茂笃 韩克利 李学初 何国钟 楼南泉 |
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| 作者单位： | [1]中国科学院大连化学物理研究所,分子反应动力学国家重 [2]中国科学院大连化学物理研究所,分子反应动力学国家重 |
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| 基金项目： | 国家自然科学基金资助项目(29953001) |
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| 摘 要： | 用266nm激光解离亚硝基苯（C6H5NO）产生光解碎片NO，并利用单光子激光诱导荧光（LIF）技术（X^2Ⅱv″=0→A^2∑^+v′=0）测得初生态光解产物NO的振转光谱。根据计算所得的模拟光谱对光解碎片NO（X，v^″＝0）的转动量子数J″进行了归属，得到了量子数最大到J″＝50．5的转动能级的相对布居，这表面光解碎片NO具有较高的转动激发。提出了C6H5NO在266nm下可能的光解机理。
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| 关 键 词： | 亚硝基苯 单光子激光诱导荧光光谱 光解动力学 一氧化氮 振转光谱 |
| 收稿时间： | 2000/6/15 0:00:00 |
Photodissociation Dynamics of Nitrosobenzene by Means of LIF |
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| Sun Julong,Li Yamin,Chen Maodu,Han Keli,Li Xuechu,He Guozhong and Lou Nanquan.Photodissociation Dynamics of Nitrosobenzene by Means of LIF[J].Chinese Journal of Chemical Physics,2001,14(2):129-134. |
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| Authors: | Sun Julong Li Yamin Chen Maodu Han Keli Li Xuechu He Guozhong and Lou Nanquan |
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| Institution: | State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics,Chinese Academy of Science, Dalian 116023,State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics,Chinese Academy of Science, Dalian 116023,State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics,Chinese Academy of Science, Dalian 116023,State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics,Chinese Academy of Science, Dalian 116023,State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics,Chinese Academy of Science, Dalian 116023,State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics,Chinese Academy of Science, Dalian 116023,State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics,Chinese Academy of Science, Dalian 116023 |
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| Abstract: | |
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| Keywords: | The photodissociation of nitrosobenzene One-photon laser-induced fluorescence spectra |
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