| 三氯一氟甲烷分子的正负离子对光解离动力学 |
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| 引用本文： | 陈刘利,田善喜,徐云峰,储根柏,刘付轶,单晓斌,盛六四.三氯一氟甲烷分子的正负离子对光解离动力学[J].化学物理学报,2011,24(3):261-266. |
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| 作者姓名： | 陈刘利 田善喜 徐云峰 储根柏 刘付轶 单晓斌 盛六四 |
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| 作者单位： | 中国科学技术大学合肥微尺度物质科学国家实验室，合肥230026;中国科学技术大学合肥微尺度物质科学国家实验室，合肥230026;中国科学技术大学合肥微尺度物质科学国家实验室，合肥230026;中国科学技术大学国家同步辐射实验室，合肥230029;中国科学技术大学国家同步辐射实验室，合肥230029;中国科学技术大学国家同步辐射实验室，合肥230029;中国科学技术大学国家同步辐射实验室，合肥230029 |
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| 摘 要： | 在CFCl3分子的同步辐射光激发正负离子解离过程中，利用负离子飞行时间质谱技术观测到了F-和Cl-(包括35Cl-和37Cl-)，测量得到了35Cl-和37Cl-在7.75～22.00 eV的负离子产额效率谱. 实验得到CFCl3→CFCl
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| 关 键 词： | 三氯一氟甲烷，离子对解离，里德堡态，负离子效率谱，飞行时间质谱 |
| 收稿时间： | 2011/3/17 0:00:00 |
Ion-Pair Photodissociation of Trichloromonofluoromethane |
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| Liu-li Chen,Shan-xi Tian,Yun-feng Xu,Gen-bai Chu,Fu-yi Liu,Xiao-bin Shan and Liu-si Sheng.Ion-Pair Photodissociation of Trichloromonofluoromethane[J].Chinese Journal of Chemical Physics,2011,24(3):261-266. |
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| Authors: | Liu-li Chen Shan-xi Tian Yun-feng Xu Gen-bai Chu Fu-yi Liu Xiao-bin Shan and Liu-si Sheng |
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| Institution: | Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China;Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China;Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China;National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China;National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China;National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China;National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China |
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| Abstract: | |
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| Keywords: | Trichloromonofluoromethane Ion-pair dissociation Rydberg state Ion-pair anion efficiency spectrum Time-of-flight mass spectrometer |
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