| 硫化钴的激光诱导荧光光谱：一个来自基态的新激发态 |
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| 引用本文： | 臧建正,张群,张德萍,秦成兵,张强,陈旸.硫化钴的激光诱导荧光光谱：一个来自基态的新激发态[J].化学物理学报,2013,26(6):701-704. |
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| 作者姓名： | 臧建正 张群 张德萍 秦成兵 张强 陈旸 |
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| 作者单位： | 中国科学技术大学合肥微尺度物质科学国家实验室，化学物理系，合肥230026;中国科学技术大学合肥微尺度物质科学国家实验室，化学物理系，合肥230026;中国科学技术大学合肥微尺度物质科学国家实验室，化学物理系，合肥230026;中国科学技术大学合肥微尺度物质科学国家实验室，化学物理系，合肥230026;中国科学技术大学合肥微尺度物质科学国家实验室，化学物理系，合肥230026;中国科学技术大学合肥微尺度物质科学国家实验室，化学物理系，合肥230026 |
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| 摘 要： | 采用激光诱导荧光技术在22400～24400 cm-1研究了超声射流冷却下的硫化钴光谱，获得了一个包含六个振动带的电子跃迁序列，该电子跃迁序列为：24.00]4△7/2-X4△7/2．新的电子态的电子组态很可能是core10σ2]4π3]11σ2]1δ3]5π3]，该电子态的所有的振动谱带都受到了其他电子态的严重微扰，通过转动分析得到了这些谱带的转动常数，同时也测量了这些谱带的寿命
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| 关 键 词： | 硫化钴，激光诱导荧光，色散荧光，电子态间的微扰 |
Laser-induced Fluorescence Spectroscopy of CoS: Identification of a New Excited State Arising from the Ground State |
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| Jian-zheng Zang,Qun Zhang,De-ping Zhang,Cheng-bing Qin,Qiang Zhang and Yang Chen.Laser-induced Fluorescence Spectroscopy of CoS: Identification of a New Excited State Arising from the Ground State[J].Chinese Journal of Chemical Physics,2013,26(6):701-704. |
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| Authors: | Jian-zheng Zang Qun Zhang De-ping Zhang Cheng-bing Qin Qiang Zhang and Yang Chen |
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| Institution: | Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China;Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China;Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China;Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China;Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China;Hefei National Laboratory for Physical Sciences at the Microscale, and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China |
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| Abstract: | |
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| Keywords: | CoS Laser-induced fluorescence Dispersed fluorescence Perturbation among states |
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