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Low-temperature synthesis of ZnO nanonails
Authors:Xubo Song  Yaohua Zhang  Xingguo Li
Institution:a Beijing National Laboratory for Molecular Sciences (BNLMS), (The State Key Laboratory of Rare Earth Materials Chemistry and Applications), College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
b Institute of Chemical Defense, Beijing 102205, China
c College of Engineering, Peking University, Beijing, 100871, China
Abstract:Wurtzite ZnO nanonails on silicon substrate were successfully synthesized by thermal vapor transport and condensation method at a low temperature without a metal catalyst. Pure Zn powders were used as raw material and O2/Ar powders as source gas. The products were characterized by scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The results show that the deposited nanostructures include aligned ZnO nanonails. The ZnO nanonails, with crystalline cap and small-diameter shafts, grow along the c-axis. The optical properties have been revealed by photoluminescence spectra. We considered that the ZnO nanonails growth is a vapor-solid process.
Keywords:A  Nanostructures  B  Vapor deposition  C  ZnO
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