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Investigations on Pr1.6Sr0.4NiO4-YSZ-Ag composite cathode for solid oxide fuel cells
Authors:Xiqiang Huang  Tingting Li  Zhen Wang  Wenhui Su
Institution:a Center for Condensed Matter Science and Technology, Department of Physics, Harbin Institute of Technology, Harbin 150001, PR China
b International Center for Materials Physics, Academia Sinica, Shenyang 110015, PR China
Abstract:Ag-network was successfully deposited by VA-EP (vacuum assisted electroless plating) method on Pr1.6Sr0.4NiO4-YSZ cathode to form (1−x) wt% Pr1.6Sr0.4NiO4wt% YSZ-Ag (x=0, 10, 20, 30, 40) (abbr. PYx-Ag) composite cathode. XRD results suggested that there was a good chemical stability between Pr1.6Sr0.4NiO4 and YSZ at temperatures below 1050 °C. PY20-Ag cathode exhibited higher exchange current density, lower overpotential and ASR (Area Specific Resistance) than PY20 cathode. At 650 °C, the ASR of PY20-Ag cathode was 2.5 Ω cm2, which was only about 42% of that of PY20, 5.9 Ω cm2. PY20-Ag can be a promising candidate for SOFC cathode.
Keywords:A  Ceramics  A  Oxides  D  Electrochemical properties
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