Low-temperature preparation and properties of ceramics with composition (1−x)CaTiO3−xPbF2−xLiF |
| |
Institution: | Faculty of Chemistry, USTHB, P.O. Box 32 El-Alia, 16311 Bab-Ezzouar, Algiers, Algeria |
| |
Abstract: | Fluorinated ceramics with initial composition (1−x)CaTiO3+xPbF2+xLiF were sintered at 950 °C. The X-ray diffraction (XRD) patterns of the samples showed the formation of a novel solid solution in the initial composition range 0⩽x⩽0.125. SEM observations were performed on fractured ceramics and DSC analyses were carried out from room temperature up to 600 °C. Three second-order phase transitions were detected for all the samples. Capacitors were prepared from the pre-sintered ceramics then dielectric measurements were performed as a function of temperature in the frequency range 102–4×107 Hz. The ε′r−T curves exhibit the profile of dielectrics for class I capacitors, however the values of tan δ are too high (tan δ⩾1%). |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|