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Synthesis of graphene oxide sheets decorated by silver nanoparticles in organic phase and their catalytic activity
Authors:Aiqin Mao  Danhui Zhang  Xia Jin  Xiaolong Gu  Xiaoqing Wei  Guojing Yang  Xiaoheng Liu
Institution:1. School of Materials Science and Engineering, Anhui Key Laboratory of Metal Materials and Processing, Anhui University of Technology, Ma’anshan, Anhui 243002, PR China;2. Zhejiang Province Key Laboratory of Soldering & Brazing Materials and Technology, PR China;3. Key Laboratory of Education Ministry for Soft Chemistry and Functional Materials, Nanjing University of Science and Technology, Nanjing 210094, China
Abstract:The graphene oxide(GO) sheets decorated by Ag nanoparticles were prepared using a liquid–liquid two-phase method at the room temperature. The synthesized samples existed in the organic phase and were characterized by X-ray diffraction, transmission electron microscopy, UV–vis spectroscopy and Raman spectra. The results demonstrate that these silver-nanoparticles with diameter of about 10 nm assembled on graphene oxide sheets are flexible and can form stable suspensions in organic phase. Raman signals of graphene oxide sheets are increased by the attached silver nanoparticles, displaying higher surface-enhanced Raman scattering activity. Furthermore, Ag/GO are found to serve as effective catalysts to activate the reduction of 4-nitrophenol (4NP) in the presence of NaBH4.
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