Properties suggesting H3+-type clusters in some metallic hydrides |
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| Authors: | D Lupu RV Bucur |
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| Institution: | Institute of Stable Isotopes, Cluj-Napoca, P.O. Box 243, Str. Donath 65-103, Romania |
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| Abstract: | The p-c-T relationships for the hydrogen-rich phase of some metallic hydrides are calculated supposing the formation of H3+ -type clusters in the metal lattice in equilibrium with the hydrogen gas. The experimental data for the hydride phase of LaNi5, Pd, Nb (H?Nb? 0.75) and U are consistent with this model. Other properties reported in literature which seem to support this model are discussed. |
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