Change of conduction mechanism with gamma dose of irradiated borosilicate glasses containing copper ions |
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Authors: | A Tawansi H Dowediar Morsi M Morsi SA Khairy |
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Institution: | Physics Department, Faculty of Science, Mansoura University, Egypt;National Research Centre, Glass Research Division, Dokki, Cairo, Egypt;Physics Department, Faculty of Science, Cairo University, Egypt |
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Abstract: | The d.c. electrical resistivity of sodium borosilicate glasses containing copper ions has been measured at the temperature range 300–623 K before and after gamma irradiation. The results obtained indicate that conduction may proceed ionically for the unirradiated glasses, with an activation energy in the range 23–24.2 Kcal/mol. Relatively low gamma doses (3.6–25 Mrads) induce two regions, separated at a critical temperature (Tc), of different activation energies. An activation energy E1, 3.4 Kcal/mol, in the temperature range from 300–370 K, and E2 16.8–20.9 Kcal/mol, in the range of higher temperatures. The mechanism suggested is that the ionic conduction is replaced by an electronic one up to about 370 K then seems to be replaced at higher temperature region by ionic-like mechanism which can be expressed by exciton-like process. High gamma doses (28.33 M rads) cause the glasses to have activation energy ranges between 19.9–22.7 Kcal/mol, which may substantiate the predominance of the proposed ionic-like mechanism.The transition region around Tc seems to be divided into three regions, precritical, critical and post-critical. |
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