添加KCl对银胶光吸收的影响

本文研究了添加KCl对两种银胶光吸收谱的影响,并与添加吡啶的情形进行了比较。结果表明KCl的加入,由于造成银颗粒表面的覆盖层而使整个光谱区的光吸收增加,消弱了原银颗粒的等离振子共振吸收,同时因银胶发生链状凝聚,原等离振子共振吸收峰发生劈裂和红移。讨论了这些变化对表面增强喇曼散射强度的影响。 关键词：

INFLUENCE OF ADDING KCl ON LIGHT ABSORPTION SPECTRA OF SILVER COLLOID

The influence of adding KCI to silver colloid on light absorption of the colloid was studied and compared with that of adding pyridine to the colloid. It was found that the light absorption was increased due to the formation of an atomic cluster layer on the Ag particle surfaces caused by adding KCI, and that the original surfaces plasmon resonance absorption was reduced. At the same time, the linear-chain aggregation caused by adding KCI lead to an apparent red shift of the plasmon resonance absorption, which sometimes was difficult to observe. The influence of these changes on SERS was also discussed.