钙钛矿CaTiO3的超高压结构研究

利用同步辐射x射线衍射和 DAC 高压技术在室温下测量了钙钛矿CaTiO₃在压力0—44.53 GPa下的结构变化.结果表明，随着压力的增加CaTiO₃的三个晶轴都受到不同程度的压缩，a,b的压缩率相近且相对比较大，c的压缩率最小，但没有证据表明有相变的发生.在压力范围内CaTiO₃的P-V关系用Murnaghan状态方程表示，设定K′0=4，得到V0=0.2245(6)nm3和K0=222(9) GPa.应用赝立方角γpc与压力的关系，初 关键词： 3')" href="#">CaTiO₃ 结构 超高压 状态方程

Study of CaTiO3 structure under high pressure

In situ high-pressure (up to 44-53 GPa) energy dispersive x-ray diffraction experiments have been carried out on CaTiO CaTiO ₃, structure, high pressure, equation of state in a diamond anvil cell at room temperature by using synchrotron radiation. Experimental data show that the a and b axes have similar compressibilities with large variation, while the c axis is less compressible with increasing pressure. However, there is no evidence of any structural transformation in this pressure range. The isothermal P-V equation of the state of CaTiO CaTiO ₃, structure, high pressure, equation of state is fitted using the Murnaghan equation of state, which yields values of V0=0.2245(6)nm 3 and K 0=222(9) GPa assuming the pressure derivative K′0=4 According to the relation of the pseudo-cubic angle γpc and pressure, the structure of CaTiO CaTiO ₃, structure, high pressure, equation of state will reduce its symmetry under hydrostatic pressure.