低扩散系数对Pd77Cu6Si17合金易非晶化的影响

采用激光熔凝技术,研究了Pd₇₇Cu₆Si₁₇合金快速凝固组织的演变规律.研究表明:随着生长速度的增大,Pd₇₇Cu₆Si₁₇合金晶体生长组织形貌发生了Pd₃Si枝晶+共晶-ξ枝晶+共晶-共晶团簇-规则共晶-非晶的转变,共晶失稳即非晶形成的临界生长速度为6 mm/s,最小层片间距为35 nm.通过与Al-25 wt% Sm,Al-32.7

Effect of low diffusion coefficient on glass phase formation in Pd77Cu6Si17 alloy

The microstructure evolution of laser rapidly solidified Pd₇₇Cu₆Si₁₇ alloy was investigated. The experimental results showed that with increasing growth velocity, a phase transition series of Pd₃Si dendrite+eutectic-ξ dendrite+eutectic-eutectic grain-regular eutectic-amorphous phase occurred. The critical velocity of amorphous transition was determined to be about 6 mm/s and the smallest lamellar spacing was 35 nm. Compared with those of Al-25 wt% Sm and Al-32.7 wt% Cu alloys, it was proposed that low diffusion coefficient is the main reason for the good glass formation ability of Pd₇₇Cu₆Si₁₇ alloy.