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全息聚合物弥散液晶材料衍射特性的优化
引用本文:张斌,刘言军,贾瑜,徐克寿.全息聚合物弥散液晶材料衍射特性的优化[J].物理学报,2003,52(1):91-95.
作者姓名:张斌  刘言军  贾瑜  徐克寿
作者单位:(1)复旦大学化学系,上海 200433; (2)复旦大学先进光子材料与器件国家重点实验室,光科学与工程系,上海 200433
基金项目:国家自然科学基金(批准号:60077003)和上海市科学技术发展基金(批准号:012261009)资助的课题.
摘    要:研究了影响全息聚合物弥散液晶(HPDLC)衍射效率的主要因素,分析了衍射效率与聚合物单体的选择、曝光强度、曝光时间、液晶含量及温度的依赖关系,从而找到最佳条件,使衍射特性得到优化.目前测得的最大衍射效率为802%.实验中还研究了扫描电镜(SEM)观察下HPDLC的表面形貌.

关 键 词:全息聚合物弥散液晶  衍射效率  相分离  表面表貌
收稿时间:4/6/2002 12:00:00 AM
修稿时间:6/7/2002 12:00:00 AM

Optimization of diffraction properties for holographic polymer dispersed liquid crystal
Zhang Bin,Liu Yan-Jun,Xu Ke Shu and Jia Yu.Optimization of diffraction properties for holographic polymer dispersed liquid crystal[J].Acta Physica Sinica,2003,52(1):91-95.
Authors:Zhang Bin  Liu Yan-Jun  Xu Ke Shu and Jia Yu
Abstract:Holographic polymer\|dispersed liquid crystal (HPDLC) is a kind of switchable volume holography. It can be manufactured according to the photo\|initiated polymerization\|induced phase separation. HPDLC is composed of parallel, periodic polymer\|rich and liquid crystal\|rich planes. The diffraction efficiency can be modulated by the application of electric field. HPDLC devices are potentially useful for optical communication, information storage and display. How to increase the diffraction efficiency is the key to application. We investigated the dependence of diffraction efficiency on the refractive index of the polymer, exposure intensity, liquid crystal loading and temperature. The best conditions were found to make the diffraction properties optimized. Now the highest diffraction efficiency was 80\^2%. The HPDLC morphologies were also observed and analyzed by scanning electron microscope (SEM).
Keywords:holographic polymer dispersed liquid crystal  diffraction efficiency  phase separation  morphology
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